Glass-to-crystal transition in the NASICON glass-ceramic system Na1+xAlxM2−x(PO4)3 (M=Ge, Ti)
Published in Journal of Non-Crystalline Solids, 2018
Multinuclear NMR follows the conversion of sodium germanophosphate and titanophosphate glasses into NASICON-type glass-ceramics for solid electrolytes. The two systems differ in aluminum coordination, phosphate environments, and sodium distributions. These observations connect local structural changes with the crystalline phases formed during heat treatment.
Citation
H. Bradtmüller, A.M. Nieto-Muñoz, J.F. Ortiz-Mosquera, A.C.M. Rodrigues, H. Eckert, “Glass-to-crystal transition in the NASICON glass-ceramic system Na1+xAlxM2−x(PO4) 3 (M=Ge, Ti)”, Journal of Non-Crystalline Solids, 2017, 489, 91−101.