Structural Studies of NaPO3-AlF3 Glasses by High-Resolution Double-Resonance Nuclear Magnetic Resonance Spectroscopy
Published in Journal of Physical Chemistry C, 2018
A combination of NMR experiments maps the local environments and atomic proximities in sodium aluminofluorophosphate glasses. The results distinguish phosphorus-bound and aluminum-bound fluorine and show how these species interact with sodium. Together, the measurements provide a structural model that goes beyond the information available from individual spectra.
Citation
H. Bradtmüller, L. Zhang, C.C. de Araujo, H. Eckert, D. Möncke, D. Ehrt, “Structural Studies of NaPO3-AlF3 Glasses by High-Resolution Double-Resonance Nuclear Magnetic Resonance Spectroscopy”, Journal of Physical Chemistry C, 2018, 122, 21579−21588.
