Structural Studies of NaPO3-AlF3 Glasses by High-Resolution Double-Resonance Nuclear Magnetic Resonance Spectroscopy

Published in Journal of Physical Chemistry C, 2018

A combination of NMR experiments maps the local environments and atomic proximities in sodium aluminofluorophosphate glasses. The results distinguish phosphorus-bound and aluminum-bound fluorine and show how these species interact with sodium. Together, the measurements provide a structural model that goes beyond the information available from individual spectra.

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Citation

H. Bradtmüller, L. Zhang, C.C. de Araujo, H. Eckert, D. Möncke, D. Ehrt, “Structural Studies of NaPO3-AlF3 Glasses by High-Resolution Double-Resonance Nuclear Magnetic Resonance Spectroscopy”, Journal of Physical Chemistry C, 2018, 122, 21579−21588.