BiF3 Incorporation in Na/Ba Mixed Network Modifier Fluoride−Phosphate Glasses: Structural Studies by Solid-State NMR and Raman Spectroscopies
Published in Journal of Physical Chemistry C, 2020
Multinuclear NMR disentangles the effects of bismuth and fluorine in fluoride–phosphate glasses for optical applications. Fluoride can terminate phosphate chains or remain associated with metal ions, while increasing bismuth fluoride content changes sodium’s local surroundings. These distinctions clarify how the additives reorganize the glass network.
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Citation
Gustavo Galleani, **Henrik Bradtmüller**, Hssen Fares, Silvia Helena Santagneli, Marcelo Nalin and Hellmut Eckert, “BiF$_3$ Incorporation in Na/Ba Mixed Network Modifier Fluoride-Phosphate Glasses: Structural Studies by Solid State NMR and Raman Spectroscopies”, Journal of Physical Chemistry C, 2020, 124, 25578−25587.